This guidance will enable applicants to adequately document toxicity information in their applications and provide project committee members consistent guidance for acceptable sources of that information. Chemical used in a cooling mechanism, such as an air conditioner or refrigerator, as the heat carrier which changes from gas to liquid and the back to gas in the refrigeration cycle. Chemical refrigerants are assigned an r number which is determined systematically according. Incorporating product design into the development of new refrigerants isaac j. Digiulio the university of oklahoma school of chemical, biological and materials engineering norman, oklahoma may 4 th, 2007 keywords. The revival of lpg refrigerants in domestic and small commercial applications is a happy accident vidal 1992. The refrigerants are numbered with an r, followed by the hfcnumber, given by the rules of the fluorocarbons numbering system. This designation indicated that it falls under the. The following is a list of refrigerants with their typeprefix, ashrae designated numbers, iupac chemical name, molecular formula, cas registry number blend name, atmospheric lifetime in years, semiempirical ozone depletion potential, net global warming potential over a 100year time horizon, occupational exposure limitpermissible exposure. The following dates and events illustrate the development of the industry and the variety.
Here are some of the desirable properties of refrigerant explained in detail. This section presents data for the thermodynamic and transport properties of refrigerants, arranged for the occasional users. A refrigerant is a fluid used in a refrigeration system to extract heat at low temperature and low pressure during evaporation and reject heat at high temperature and high pressure during condensation. This standard is under continuous maintenance by a standing standard project committee sspc for which. It is intended to be used with other relevant safety standards such as iso 5149, iec 60335224 and iec 60335240. Figure shows the classification of fluids used as refrigerants in vapor compression refrigeration systems. Merging the transition to next generation hvac refrigerant. Refrigerants temperature and pressure charts temperature and pressure chart for refrigerants r22, r410a, r12, r4a, r401a, r409a, r502, r404a, r507a, r408a and r402a tag search en. Used as blend component with other refrigerants to lower gwp. Designation and safety classification of refrigerants approved by the ashrae standards committee on january 29, 2003. A further service blend is offered under the designation r4a isceon mo49. Since a large number of refrigerants have been developed over the years for a wide variety of applications, a numbering system. The high efficiency of natural refrigerants also means that they make a lower indirect contribution to global warming. Tables listing the refrigerant designations are included.
Which group of three refrigerants are considered low pressure refrigerants under the clean air act rules. The refrigerants r4a and r410a were both introduced as. The designation rxyz is determined by the chemical composition of the molecule, as described below. Examples of secondary refrigerants include water, air, hydrocarbons, ammonia and carbon dioxide, which are more environmentally benign than traditional refrigerants such as hcfcs. Incorporating product design into the development of new. Natural refrigerants are chemicals which occur in natures biochemical processes. Ashrae standard designation and safety classification of. While r4a and r410a are both environmentally conscious hydrochlorofluorocarbon refrigerants, the two are otherwise dissimilar. Hydrocarbon refrigerants are natural replacements for cfc, hfc and hcfc refrigerant gases, and are. Used as blend component with other refrigerants to lower gwp depending on the composition and percentage of 2l material, resulting blends are classified as either a1 nonflammable or a2l. Refrigerants may be divided into three classes according to their manner of absorption or extraction of heat from the substances to be refrigerated. The primary refrigerants are those that pass through the processes of compression, cooling or condensation, expansion and evaporation or warming up during cyclic processes.
According to an international agreement, refrigerants are represented by the letter r as in refrigerants followed by a two or threedigit number and, in some cases, one or two letters. Standard 34 ashrae standard 34, designation and safety classification of refrigerants, establishes a simple means of referring to common refrigerants rather than by their chemical name, formula, or trade name. The total temperature glide of a refrigerant blend is. A comparison between refrigerants used in air conditioning. New refrigerants designation and safety classifications emerson. The refrigerants have a thermodynamic property charge. Refrigerants are widely used in refrigeration cycle where cooling effect below the atmospheric temperatures are needed. History modern refrigeration methods, as distinguished from the use of ice and snow, go back to the early part of the 19th century. Our servers in the cloud will handle the pdf creation for you once you have combined your files.
They do not deplete the ozone layer and make a negligible or zero in the case of r717 ammonia contribution to global warming. Product design, group contribution theory, refrigerant design. Actually, i got some office projects files in pdf and i was looking for the way by which i can manage them all in one place, firstly i put them in one folder but that was also hectic to open a number of files again and again to search different terms. Working principle under this heading, we have the primary or common refrigerants and the secondary refrigerants. In most cases, they have a very narrow application window and lower capacity. It is now widely agreed that only percentage of poe is required to ensure. To merge pdfs or just to add a page to a pdf you usually have to buy expensive software. The earliest mechanical refrigeration used air as a working fluid. The primary purpose of refrigeration is producing and maintaining the.
The basis of the designation of the refrigerants fluids is based on a numbering system 1 pure fluorocarbons hfc refrigerants and their blends the refrigerants are numbered with an r, followed by the hfcnumber, given by the rules of the fluorocarbons numbering system. New tables of the reading and writing arabic pdf thermodynamic properties of dupont. The tables contained on this page list approved refrigerant numbers from ansiashrae 342019, designation and safety classification of refrigerants, the latest edition of standard 34, which describes a shorthand way of naming refrigerants and assigns safety classifications based on toxicity and flammability data. Natural refrigerants was developed as a joint effort between the national renewable energy laboratory nrel and cta architects engineers. Refrigerants can be broadly classified based on the following. This article deals with the refrigerants used in steadystate sys tems belonging to. Engineers had known since the 1920s that lpg refrigerants performed well and in the 1980s refrigerator manufacturers again tested them kuijpers et al. Designation and safety classification of refrigerants ansiashrae addendum i to ansiashrae standard 342004 approved by the ashrae standards committee on january 27, 2007. The purpose of this standard is to establish purity specifications, to verify composition, and to specify the associated methods of testing for acceptability of the refrigerants listed in section 2. The constituents consist of the chlorine free substances r4a. Document title guidance relevant to flammable refrigerants iso817.
From the number one can get some useful information about the type of refrigerant, its chemical composition, molecular weight etc. One proper method of identification is referring to a refrigerant by its ansiashrae designation. Designation of refrigerants since a large number of refrigerants have been developed over the years for a wide variety of applications, a numbering system has been adopted to designate various refrigerants. New, natural and alternative refrigerants by dr s f pearson of star refrigeration limited introduction it is an honour to be invited to present this paper despite the rather daunting title. Properties of refrigerants n low boiling point and high latent heat of vaporization n dense vapor n low toxicity n non flammable n low miscibility with oil n low cost ammonia n has good heat transfer properties n not miscible with oil n but n toxic n flammable n corrosive to. Tables listing the refrigerant designations, safety classifications and the refrigerant concentration limits are included based on data made available. Whenever we choose them for particular use properties of refrigerants also plays a vital role in economic and environmental friendly application.
With a nonmiscible combination oil logging can occur, which impacts compressor life and performance. It establishes a uniform system for assigning reference numbers, safety classifications, and refrigerant concentration. Pdf merge combine pdf files free tool to merge pdf online. Most common commercial refrigerants are the chlorofluorocarbons cfcs which, because of their high ozone damaging potential, are being phased out. At room temperature r410a has a pressure of nearly 200 psi, while r4a is around 70 psi. The designation rxyz is determined by the chemical composition of the molecule, as. One of two situations will occur, depending on how strongly the different molecules are attracted to each other. Service refrigerants contain hcfc as blend component. This standardized numbering system was first developed by e. This publication is designed to provide accurate and authoritative information.
Tables listing the refrigerant designations, safety classifications and the refrigerant. This project was made possible with american recovery and reinvestment act of 2009 funds. The following documents include guidance on systems using flammable refrigerants. Area position on training and certification of low gwp refrigerants 1 the future phasedown of hfcs will lead to a higher use of alternative refrigerants low gwp refrigerants. Chapter 3 refrigerants and mixture preparation refrigeration is the process of removing heat from the space to be cooled and transferring it to a place where it is unobjectionable. Blends are made up of two or more single component refrigerants. It also establishes a system for assigning a safety classification to refrigerants based on toxicity and flammability data, and provides a means of determining the refrigerant concentration limit. Some refrigerants claim to be nooilchange solutions. These refrigerants cool by temperature change or sensible heat, the quantity of heat being. New refrigerants designation and safety classifications.
Addenda to designation and safety classifications of. Select multiple pdf files and merge them in seconds. Halocarbon refrigerants halocarbon refrigerant are all synthetically produced and were developed as the freon family of refrigerants. The following is a list of refrigerants with their type prefix, ashrae designated numbers. Download and install the soda pdf desktop app to edit, compress, split, secure and merge pdf files offline. Fluids suitable for refrigeration purposes can be classified. Since then it has been adopted by ansiashrae as part of standard 34 number designation and safety classification of refrigerants. By steve kujak, member ashrae flammability and new refrigerant ptions increasing concerns about the impact of refrigerants on the environment and on. Refrigerants pdf classify refrigerants into primary and secondary, and discuss the important. A numbering system is being used to designate various refrigerants. Describe the numbering system used for designating refrigerants section. It does not present official positions of the society nor reflect society policy. Lesson 1 covers a basic understanding of refrigerants, including the history of refrigerants, terminology, and refrigerants types such as cfc, hcfc, hfc, natural refrigerants, and blends zeotrope and azeotrope. Secondary refrigerants allow the amounts of environmentally harmful primary refrigerants to be minimized and contained in a restricted area.
The facts on hydrocarbon refrigerants hydrocarbons are natural, non toxic, non ozone depleting replacements for cfc refrigerants, importation and production of which were banned from december 31st 1995. Low gwp refrigerants have issues on safety, flammability, toxicity and high pressure which will need to be properly considered when handling those refrigerants. Originally the title given was new and alternative refrigerants but i was also asked to. Designation and safety classification of refrigerants. This class includes refrigerants that cool by phase change typically boiling, using the refrigerant s latent heat class 2.
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